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id="4nqxx5o52i" class="ly_NyNewsdetail"> <h1 class="NyNewsdetail_title">柱狀沸石分子篩內(nèi)部的孔穴可起到吸附分子的作用</h1> <div id="4nqxx5o52i" class="NyNewsdetail_tips">更新時間：2022-05-26 點擊次數(shù)：1644</div> <div id="4nqxx5o52i" class="NyNewsdetail_con"> <p>沸石礦物有很廣的分布。特別多見于由火山碎屑形成的沉積巖石中，在土壤中也有發(fā)現(xiàn)。</p><p>分子篩是一種具有立方晶格的硅鋁酸鹽化合物。分子篩具有均勻的微孔結(jié)構(gòu)，它的孔穴直徑大小均勻，這些孔穴能把比其直徑小的分子吸附到孔腔的內(nèi)部，并對極性分子和不飽和分子具有優(yōu)先吸附能力，因而能把極性程度不同，飽和程度不同，分子大小不同及沸點不同的分子分離開來，即具有“篩分"分子的作用，故稱分子篩。由于分子篩具有吸附能力高，熱穩(wěn)定性強(qiáng)等其它吸附劑所沒有的優(yōu)點，使得分子篩獲得廣泛的應(yīng)用。</p><p>沸石對有機(jī)污染物的吸附能力主要取決于有機(jī)物分子的極性大小和分子直徑。小分子比大分子易被吸附，極性分子較非極性妃子易被吸附，在水中由于存在不同的物質(zhì)(如有機(jī)物分子、金屬離子和水分子)，他們的極性強(qiáng)弱和分子大小均不相同，在吸附時就會產(chǎn)生競爭現(xiàn)象。</p><p>特點</p><p>1、具有*，深度干燥分離度；</p><p>2、可以有效地避免分離時所產(chǎn)生共吸附現(xiàn)象，提高產(chǎn)品得率；</p><p>3、可以在同一系統(tǒng)中同時完成干燥和物質(zhì)的純化；</p><p>4、在較高的溫度條件下，同樣具有一定的吸附容量；</p><p>5、分子篩系統(tǒng)較其他干燥和分離裝置，設(shè)備投資低，運(yùn)轉(zhuǎn)成本低。</p><p>沸石分子篩在各種不同的酸性催化反應(yīng)中，能夠提供很高的活性和不尋常的選擇性，且絕大多數(shù)反應(yīng)是由分子篩的酸性引起的，酸度及其酸強(qiáng)度分布是分子篩的重要參數(shù)。研究表明，分子篩中B 酸來源于骨架四面體鋁，而L 酸主要來源于非骨架六面體鋁，所以分子篩中Al 的含量及其分布與分子篩的表面酸性物質(zhì)密切相關(guān)，故可采用分子篩的脫鋁和補(bǔ)鋁等二次水熱處理，得到理想的硅鋁比的分子篩。此外，分子篩的酸性還受取代金屬離子影響，由于多價金屬離子的水解作用，導(dǎo)致催化劑表面酸中心重新分布。</p><p><br/></p> </div> <div id="4nqxx5o52i" 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